/LC.GIF&client=easterncarolinaedu)
Encyclopedia of radicals in chemistry, biology, and materials / editors, Chryssostomos Chatgilialoglu, Armido Studer.
| Other author | Chatgilialoglu, Chryssostomos. |
| Other author | Studer, Armido. |
| Format | Book |
| Publication Info | Chichester, West Sussex ; Hoboken, N.J. : John Wiley & Sons, 2012. |
| Description | 4 volumes (xxx, 2293 pages) : illustrations, some color ; 26 cm |
| Supplemental Content | Cover image |
| Subjects |
| Contents | Basic concepts and methodologies. The history of free radical chemistry / Thomas T. Tidwell -- Overview of radical initiation / Jacques Lalevée and Jean Pierre Fouassier -- Basic concepts on radical chain reactions / Michael S. Sherburn -- Thermochemistry and hydrogen transfer kinetics / Andreas A. Zavitsas -- Radical kinetics and clocks / Martin Newcomb -- Radical rearrangements : Ester-substituted radicals and hydrogen atom migrations / Kaname Sasaki, Ian Cumpstey and David Crich -- Analysis of radicals by EPR / John C. Walton -- Structures and reactivity of radicals followed by magnetic resonance / Alexandra Yurkovskaya, Olga Morozova and Georg Gescheidt -- Matrix isolation of radicals / Artur Mardyukov and Wolfram Sander -- Supramolecular radical chemistry / Marco Lucarini -- Redox properties of radicals / David C. Magri and Mark S. Workentin -- Photo induced radical reactions / Julia Perez-Prieto and Miguel A. Miranda -- Radical cation/anion and neutral radicals : A comparison / Amber N. Hancock and J.M. Tanko -- The SRN1 reaction / Javier I. Bardagí, Victoria A. Vaillard and Roberto A. Rossi -- Photoinduced reactions of radical ions via charge separation / Shunichi Fukuzumi and Kei Ohkubo -- Radiation-induced radical reactions / Krzysztof Bobrowski -- Free radical chemistry in room-temperature ionic liquids / Ilya A. Shkrob and James F. Wishart -- Radical stability-Thermochemical aspects / Johnny Hioe and Hendrik Zipse -- Radical chemistry in the gas phase / Christian Alcaraz, Ingo Fischer and Detlef Schröder -- Atmospheric radical chemistry / Paul H. Wine and J. Michael Nicovich -- |
| Contents | Synthetic strategies and applications. Tin hydrides and functional group transformations / Hannelore Jasch and Markus R> Heinrich -- Silanes as reducing reagents in radical chemistry / Chryssostomos Chatgilialoglu and Vitaliy I. Timokhin -- Boron in radical chemistry / Philippe Renaud -- Intramolecular homolytic substitutions in synthesis / Sara H. Kyne and Carl H. Schiesser -- Stereoselective radical reactions / Yong-Hua Yang and Mukund P. Sibi -- Unusual cyclizations / Kerry Gilmore and Igor V. Alabugin -- Radical cascade reactions . Alexandre Baralle, Abdulkader Baroudi...[et. al.] -- Main-group elements in radical chemistry / Alexander Baralle, Abdulkader Barouid...[et. al.] -- Organic electron donors / John A. Murphy -- Organic synthesis using samarium diiodide / Susannah C. Coote, Robert A. Flowers II...[et. al.] -- Manganese(III) acetate, CAN, and Fe(III) salts in oxidative radical chemistry / Jonathan W. Burton -- Halogen and chalcogen transfer chemistry / Chaozhong Li -- Xanthates and related derivatives as radical precursors / Samir Z. Zard -- Epoxides in titanocene-mediated and -catalyzed radical reactions / Andreas Gansäuer and André Fleckhaus -- Transition metals and radicals / Hideki Yorimitsu -- Unusual radical acceptors / Piero Spagnolo and Daniele Nanni -- Radical arylations / Santiago E. Vaillard and Armido Studer -- Nitroxides in synthetic radical chemistry / Chittreeya Tansakul and Rebecca Braslau -- Radicals and carbohydrates / Inés Pérez-Martín and Ernesto Suárez -- Electrochemically initiated radical reactions / Martin A. Bohn, Anna Paul and Gerhard Hilt -- Synthetic radical photochemistry / Emmanuel Riguet and Norbert Hoffmann -- Radical chemistry by using flow microreactor technology / Takahide Fukuyama and Ilhyong Ryu -- |
| Contents | Chemical biology. Biological chemistry of reactive oxygen species / Christine C. Winterbourn -- Reactions of small reactive species with DNA / Nicholas E. Geacintov and Vladimir Shafirovich -- Oxidatively generated nucleobase modifications in isolated and cellular DNA / Jean Cadet, Theirry Douki, Didier Gasparutto...[et. al.] -- Oxidatively formed sugar radicals in nucleic acids / Thanasis Gimisis and Chryssostomos Chatgilialoglu -- Understanding DNA radicals employing theory and electron spin resonance spectroscopy / Amitava Adhikary, Anil Kumar...[et. al.] -- Charge transfer in DNA / Mamoru Fujitsuka and Tetsuro Majima -- Oxidative transfer in DNA / Michael J. Davies -- Radical-based damage of sulfur-containing amino acid residues / Christian Schöneich -- Electron transfer in peptides and proteins / Bernd Giese, Sonja Eckhardt and Miriam Lauz -- Radical enzymes / Wolfgang Buckel and Bernard T. Golding - Theoretical studies of radical enzymes / Gregory M. Sandala, David M. Smith and Leo Radom -- Lipid Peroxidation / Etsuo Niki -- Lipid Isomerization / Carla Ferreri and Chryssostomos Chatgilialoglu -- Antioxidants in chemistry and biology / Luca Valgimigli and Derek A. Pratt -- Free radicals and metabolic disorders / Guy Cohen, Yael Riahi and Shlomo Sasson -- |
| Contents | Polymers and materials. Radical polymerization in industry / Peter Nesvadba -- Kinetics of polymerizations / Michael Buback and Gregory T. Russell -- Fundamentals of controlled/living radical polymerization . Krzysztof Matyjaszewski -- Nitroxide-mediated polymerization and its applications / Didier Gigmes and Sylvain R.A. Marque -- Atom transfer radical polymerization (ATRP) and addition (ATRA) and applications / Tomislav Pintauer and Krzysztof Matyjaszewski -- Reversible addition fragmentation chain transfer (RAFT) polymerization : Mechanism, process and applications / Christopher Barner-Kowollik, James P. Blinco...[et. al.] -- Sb, Bi, Te, and I-transfer polymerization and applications / Shigeru Yamago and Eiichi Kayahara -- Spin labels and spin probes / David Bardelang, Micaël Hardy, Olivier Ouari and Paul Tordo -- Radical thiol-x click chemistry / Niels ten Brummelhuis and Helmut Schlaad -- Conducting polymers : Applications in electronics and photovoltaics / Huanli Dong and Wenping Hu -- Silicon radical surface chemistry / Bart Rijksen, Mabel A. Caipa Campos...[et. al.] -- Persistent and stable silyl radicals / Boris Tumanskii, Miriam Karni and Yitzhak Apeloig -- Physical properties of thiazyl radicals toward conductive and magnetic materials / Kunio Awaga -- Polyradicals in batteries / Kenichi Oyaizu and Hiroyuki Nishide -- Radical chemistry on fullerenes / Manolis D. Tzirakis and Michael Orfanopoulos -- A paradigm for the radical-mediated photochemical synthesis of metal nanostructures / Juan C. Scaiano, Kevin G. Stamplecoskie...[et. al.]. |
| Abstract | In recent years, free radicals have played an important role in various disciplines, ranging from organic synthesis to biology and medicine, polymer chemistry and materials science. The aim of this handbook is to offer for the first time a description of free radicals within an interdisciplinary and multidisciplinary context, connecting structural characteristics and chemical properties to their applications in different areas of chemistry and related disciplines. The Handbook covers not only basic concepts and chemical synthesis, but also touches on various aspects concerning the role of free radicals in materials and life sciences. The reader will find a balanced contribution of topics related to free radicals covering for example, their role in proteomics, genomics and lipidomics as well as their enormous potential in synthesis and technology. The Handbook will be interesting for anybody working in the field of free radicals in the broadest sense. It will address scientists who want to enter the interdisciplinary field of free radicals. In particular, it is aimed primarily at chemists and life science researchers who want to gain a wider and deeper understanding of free radicals which will allow them to apply free radicals in their own scientific field. The book consists of four themed volumes: Basic Concepts & Methodologies, Synthetic Strategies & Applications, Chemical Biology, Polymers & Materials. Within the volumes the chapters will also be thematically structured. |
| Bibliography note | Includes bibliographical references and indexes. |
| LCCN | 2011040417 |
| ISBN | 9780470971253 (set) |
| ISBN | 0470971258 (set) |