Advanced hierarchical nanostructured materials / edited by Qiang Zhang and Fei Wei.

Other author Zhang, Qiang (Associate Professor of Chemical Engineering
Other author Wei, Fei, 1962
Format Electronic
Publication InfoWeinheim, Germany : Wiley-VCH, Verlag GmbH & Co. KGaA, [2014]
Descriptionxix, 485 pages illustrations (some color) 25 cm
Supplemental ContentFull text available from Ebook Central - Academic Complete
Subjects
Nanostructured materials

Physical mediumillustrations
Contents Machine generated contents note: 1. Structural Diversity in Ordered Mesoporous Silica Materials / Daliang Zhang -- 1.1. Introduction -- 1.2. Electron Crystallography and Electron Tomography -- 1.2.1. Electron Crystallography -- 1.2.2. Electron Tomography -- 1.3. Diverse Structures of Ordered Mesoporous Silicas -- 1.3.1. 2D Hexagonal Structures with Cylindrical Channels -- 1.3.2. 3D Mesoporous Structures with Cage-Type Pores -- 1.3.3. Bi-Continuous Mesoporous Structures -- 1.3.4. Tri-Continuous Mesoporous Structure IBN-9 -- 1.3.5. Low-Symmetry Mesoporous Structures -- 1.3.6. Transition and Intergrowth of Different Mesoporous Structures -- 1.4. Outlook -- References -- 2. Hierarchically Nanostructured Biological Materials / Helmut Colfen -- 2.1. Introduction -- 2.2. "Bottom-Up" Design Scheme -- 2.3. Organic -- Inorganic Interfaces -- 2.4. Engineering Principles in Biological Materials -- 2.4.1. Anisotropy -- 2.4.2. Effects of Scaling -- 2.4.3. Organizing Defects and Damage in Biological Materials.
Contents 2.4.4. Mesocrystalline Schemes in Short- to Long-Range Organization -- 2.4.5. Hierarchical Structuring and Its Properties -- 2.5. Model Hierarchical Biological Systems and Materials -- 2.5.1. Nacre -- 2.5.2. Wood -- 2.5.3. Bone -- 2.5.4. Diatoms -- 2.5.5. Butterfly Wings -- 2.5.6. Glass Sponge -- 2.5.7. Adult Sea Urchin Spine -- 2.5.8. Red Coral -- 2.6. Conclusions and Outlook -- Acknowledgments -- References -- 3. Use of Magnetic Nanoparticles for the Preparation of Micro- and Nanostructured Materials / Marco Lattuada -- 3.1. Introduction -- 3.2. Preparation of Superparamagnetic Nanocolloids -- 3.2.1. Synthesis of Magnetic Nanocrystals -- 3.2.2. Synthesis of Polymer-Magnetic Nanocomposite Particles and Magnetic Nanoclusters -- 3.2.3. Summary -- 3.3. Magnetic Gels -- 3.3.1. Summary -- 3.4. Self-Assembly of Magnetic Nanoparticles, Nanoclusters, and Magnetic-Polymer Nanocomposites -- 3.4.1. Assembly in 1-D Structures -- 3.4.2. Assembly in Higher Dimensional Structures -- 3.4.3. Summary -- 3.5. Magnetic Colloidal Crystals -- 3.5.1. Summary.
Contents 3.6. Concluding Remarks -- Acknowledgment -- References -- 4. Hollow Metallic Micro/Nanostructures / Lin Guo -- 4.1. Introduction -- 4.2. Synthetic Methods for 1-D Hollow Metallic Micro/Nanostructures -- 4.2.1. Template-Directed Approach -- 4.2.1.1. Hard Template Methods -- 4.2.1.2. Sacrificial Templates -- 4.2.1.3. Soft Template Methods -- 4.2.2. Template-Free Methods -- 4.2.3. Electrospinning Technique -- 4.3. Synthetic Methods for 3-D or Nonspherical Hollow Metallic Micro/Nanostructures -- 4.3.1. Hard Template Strategy -- 4.3.2. Sacrificial Template Strategy -- 4.3.3. Soft Template Strategy -- 4.3.4. Template-Free Strategy -- 4.3.4.1. Ostwald Ripening -- 4.3.4.2. Kirkendall Effect -- 4.4. Potential Applications of Hollow Metallic Micro/Nanostructures -- 4.4.1. Lithium-Ion Batteries -- 4.4.2. Magnetic Properties -- 4.4.3. Sensors -- 4.4.4. Catalytic Properties -- 4.5. Conclusions and Outlook -- Acknowledgments -- References -- 5. Polymer Vesicles / Jianzhong Du -- 5.1. Introduction -- 5.2. Vesicle Formation.
Contents 5.3. Smart Polymer Vesicles -- 5.3.1. pH-Responsive Vesicles -- 5.3.2. Thermoresponsive Vesicles -- 5.3.3. Voltage-Responsive Polymer Vesicles -- 5.3.4. Sugar-Responsive Vesicles -- 5.3.5. Photoresponsive Vesicles -- 5.4. Applications -- 5.5. Summary and Outlook -- Acknowledgments -- References -- 6. Helical Nanoarchitecture / Fei Wei -- 6.1. Introduction -- 6.2. Fabrication of Organic Helical Nanostructures -- 6.2.1. Helical Micelles from Staggered Stacking -- 6.2.2. Helical Micelle-Like Copolymers -- 6.2.3. Helical Organic Nanostructures by Postsynthetic Processes -- 6.3. Fabrication of Inorganic Helical Nanostructures -- 6.3.1. Templated Methods -- 6.3.1.1. Organic Templates -- 6.3.1.2. Inorganic Templates -- 6.3.1.3. Backfilling of Inorganic Materials -- 6.3.2. Solution-Based Reactions -- 6.3.2.1. Staggered Stacking -- 6.3.2.2. Space Confinement -- 6.3.3. Catalytic Deposition -- 6.3.3.1. Helical Carbon Nanomaterials from Anisotropic Growth Mechanism -- 6.3.3.2. Helical Oxide Nanostructures from Electrostatic Mechanism.
Contents 6.3.3.3. Helical Crystals from Screw-Dislocation-Driven Growth Mechanism -- 6.3.4. Postsynthetic Methods -- 6.3.4.1. Electron Beam Irradiation -- 6.3.4.2. Glancing Angle Deposition -- 6.3.4.3. Untwisting of Nanowires -- 6.3.4.4. Curving of a Double Layer -- 6.3.4.5. Buckling of Nanowires under Confinement -- 6.3.4.6. Tilting of Nanopillars under Capillary Forces -- 6.4. Properties of Helical Nanostructures -- 6.4.1. Mechanical Properties -- 6.4.2. Electromagnetic Properties -- 6.4.3. Optical Properties -- Summary -- References -- 7. Hierarchical Layered Double Hydroxide Materials / Xue Duan -- 7.1. Introduction -- 7.2. Preparation of Hierarchical LDHs -- 7.2.1. LDH-Based Belt/Rod-Like Structures -- 7.2.1.1. Reverse Microemulsion Synthesis -- 7.2.1.2. Topotactic Intercalation -- 7.2.2. LDH-Based Nano/Microspheres -- 7.2.2.1. Sacrificial Template Method -- 7.2.2.2. Spray-Drying Method -- 7.2.3. LDH-Based Core-Shell Structures -- 7.2.3.1. Layer-By-Layer (LBL) Assembly -- 7.2.3.2. Coprecipitation Method -- 7.2.3.3. In Situ Growth.
Contents 7.2.4. LDHs as Substrate to the Growth of Hierarchical Structures -- 7.2.4.1. Solution-Based Chemical Synthesis -- 7.2.4.2. CVD Deposition -- 7.3. Properties of Hierarchical LDHs -- 7.3.1. Hierarchical LDHs as Absorbents -- 7.3.2. Hierarchical LDHs as Catalysts and Supports -- 7.3.3. Hierarchical LDHs as Electrochemical Energy-Storage Materials -- 7.3.3.1. Supercapacitors -- 7.3.3.2. Lithium-Ion Batteries -- 7.3.4. Hierarchical LDHs as Drug-Delivery System -- 7.4. Summary and Outlook -- Acknowledgments -- References -- 8. Hierarchically Nanostructured Porous Boron Nitride / Samuel Bernard -- 8.1. Introduction -- 8.2. Synthesis of Mesoporous Boron Nitride -- 8.2.1. Exo-Templating Synthesis -- 8.2.2. Endo-Templating Approach -- 8.2.3. Direct Synthesis -- 8.3. Synthesis of Microporous Boron Nitride -- 8.4. Synthesis of Boron Nitride with Hierarchical Porosity -- 8.4.1. Synthesis of Hierarchical Micro- and Meso-porous Boron Nitride -- 8.4.1.1. Non-Template Methods -- 8.4.1.2. Template Methods -- 8.4.2. Synthesis of Hierarchical Macro-, Meso-, and Micro-porous Boron Nitride.
Contents 8.4.2.1. The Structure-Director Route -- 8.4.2.2. Sintering of Powder -- 8.4.2.3. Direct Route -- 8.5. BN Nanosheets (BNNSs) -- 8.6. Conclusion -- References -- 9. Macroscopic Graphene Structures: Preparation, Properties, and Applications / Xiaodong Chen -- 9.1. Introduction -- 9.2. Preparation of Graphene -- 9.3. The Preparation and Properties of Graphene Macroscopic Structures -- 9.3.1. Vacuum Filtering -- 9.3.1.1. Graphene Macroscopic Structures -- 9.3.1.2. Graphene-Based Macroscopic Hybrid Structures -- 9.3.2. Template-Assisted Growth -- 9.3.2.1. Graphene Macroscopic Structures -- 9.3.2.2. Graphene-Based Macroscopic Hybrid Structures -- 9.3.3. Chemical Self-Assembly Method -- 9.3.3.1. Graphene Macroscopic Structures -- 9.3.3.2. Graphene-Based Macroscopic Hybrid Structures -- 9.3.4. Electrophoretic Method -- 9.3.4.1. Graphene Macroscopic Structures -- 9.3.4.2. Graphene-Based Macroscopic Hybrid Structures -- 9.3.5. Layer-by-Layer Method -- 9.3.5.1. Graphene Macroscopic Structures -- 9.3.5.2. Graphene-Based Macroscopic Hybrid Structures -- 9.3.6. Other Methods -- 9.3.6.1. Leavening Strategy.
Contents 9.3.6.2. Centrifugal Evaporation -- 9.3.6.3. Mechanical Cavitation -- Chemical Oxidation Approach -- 9.3.6.4. Self-Assembly at a Liquid -- Air Interface -- 9.4. Applications of Graphene Macroscopic Structures -- 9.4.1. Energy Storage -- 9.4.1.1. Supercapacitors -- 9.4.1.2. Lithium-Ion Battery -- 9.4.1.3. Hydrogen Storage -- 9.4.2. Selective Absorption -- 9.4.3. Photocatalytic Activities -- 9.4.4. Electrochemical Sensing -- 9.4.5. Actuator -- 9.4.6. Bio-Applications -- 9.5. Conclusions and Outlook -- References -- 10. Hydrothermal Nanocarbons / Maria-Magdalena Titirici -- 10.1. Introduction -- 10.2. Templating -An Opportunity for Pore Morphology Control -- 10.2.1. Hard Templating in HTC -- 10.2.2. Soft Templating HTC -- 10.2.3. Naturally Inspired Systems: The Use of Natural Templates -- 10.3. Carbon Aerogels -- 10.3.1. Ovalbumin/Glucose-Derived HTC Carbogels -- 10.3.2. Borax-Mediated Formation of HTC Carbogels from Glucose -- 10.3.3. Carbogels from the Hydrothermal Treatment of Sugar and Phenolic Compounds -- 10.3.4. Emulsion-Templated "Carbo-HIPEs" from the Hydrothermal Treatment of Sugar Derivatives and Phenolic Compounds.
Contents 10.4. Hydrothermal Carbon Nanocomposites -- 10.4.1. Coating HTC onto Preformed Nanostructures -- 10.4.2. Post-Synthetic Decoration of HTC with Inorganic Nanostructures -- 10.4.3. One-Step HTC Synthetic Method -- 10.4.4. HTC as Sacrificial Templates for Inorganic Porous Materials -- 10.5. Hydrothermal Carbon Quantum Dots -- 10.6. Summary and Outlook -- References -- 11. Hierarchical Porous Carbon Nanocomposites for Electrochemical Energy Storage / Donghai Wang -- 11.1. Introduction -- 11.2. Types of Porous Structures -- 11.2.1. Pore Size -- 11.2.2. Zero-Dimensional Porous Structures -- 11.2.3. One-Dimensional Porous Structures -- 11.2.4. Two-Dimensional Porous Structures -- 11.2.5. Three-Dimensional Porous Structures -- 11.3. Synthesis of Porous Structures.
Contents 11.3.1. Hard Templating -- 11.3.1.1. Inorganic Hard Templating -- 11.3.1.2. Organic Hard Templating -- 11.3.1.3. Other Hard Templating Approaches -- 11.3.2. Soft Templating -- 11.3.2.1. Surfactant-Based Soft Templating -- 11.3.2.2. Emulsion-Based Soft Templating -- 11.3.3. Non-Templating Methods -- 11.3.3.1. Carbon Activation -- 11.3.3.2. Pyrolysis of Porous Carbon Precursors -- 11.3.3.3. Assembly of Porous Structures from Premade Particles -- 11.3.4. Generating the Composite -- 11.3.4.1. Coating and Loading -- 11.3.4.2. In Situ Synthesis -- 11.4. Applications of Hierarchically Porous Carbon Composites -- 11.4.1. Lithium Batteries -- 11.4.1.1. Olivine Cathodes.
Contents 11.4.1.2. Lithium-Sulfur Battery Cathodes -- 11.4.1.3. Carbon Anodes -- 11.4.1.4. Metal Oxide Anodes -- 11.4.1.5. Silicon Anodes -- 11.4.2. Supercapacitors -- 11.4.2.1. Electric Double-Layer Capacitors -- 11.4.2.2. Pseudocapacitors -- 11.5. Summary and Conclusions -- References -- 12. Hierarchical Design of Porous Carbon Materials for Supercapacitors / Da-Wei Wang -- 12.1. Introduction -- 12.2. Capacitance: Electrostatic Storage -- 12.2.1. Pore Wall Structure -- 12.2.2. Pore Size -- 12.3. Ion Accessibility: Porosity and Surface Wettability -- 12.3.1. Porosity -- 12.3.2. Wettability -- 12.4. Conclusion -- References -- 13. Nanoscale Functional Polymer Coatings for Biointerface Engineering / Meng-Yu Tsai -- 13.1. Introduction -- 13.2. Synthesis of Precursors -Substituted-[2.2]paracyclophanes.
Contents 13.3. Synthesis of Functionalized Poly-p-Xylylenes via CVD Polymerization -- 13.4. Surface Bioconjugate Chemistry by Using Functionalized Poly-p-Xylylenes -- 13.4.1. Poly[(4-Formyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.2. Poly[(4-Ethynyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.3. Poly[(4-Aminomethyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.4. Poly[(4-Benzoyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.5. Poly[(4-N-Maleimidomethyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.6. Poly[(Carboxylic Acid Pentafluorophenol Ester-p-Xylylene)-co-(p-Xylylene)] -- 13.4.7. Poly[(4-Hydroxymethyl-p-Xylylene)-co-(p-Xylylene)] -- 13.4.8. Poly[(4-Vinyl-p-Xylylene)-co-(p-Xylylene)] -- 13.5. Multifunctional and Gradient Poly-p-Xylylenes -- 13.6. Outlook -- References.
Bibliography noteIncludes bibliographical references and index.
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LCCN 2023548052
ISBN9783527333462 hardcover

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