Catalytic kinetics chemistry and engineering / Dmitry Yu. Murzin and Tapio Salmi.

Author/creator Murzin, Dmitry, 1963-
Other author Salmi, Tapio.
Format Electronic
EditionSecond edition.
Publication InfoAmsterdam ; Boston : Elsevier, [2016]
Descriptionxii, 740 pages : illustrations (some color) ; 24 cm
Supplemental ContentFull text available from eBook - Chemical Engineering 2016 [EBCCE16]
Subjects

Contents Machine generated contents note: 1.1. History -- 1.2. Catalysis -- 1.3. Formal Kinetics -- 1.4. Acquisition of Kinetic Data -- 1.5. Kinetics and Thermodynamics -- 1.6. Examples and Exercises -- Reference -- 2.1. Homogeneous Catalysis -- 2.2. Heterogeneous Catalysis -- 2.3. Organocatalysis -- 2.4. Examples and Exercises -- Reference -- 3.1. Reaction Rate Theory -- 3.2. Elementary Reactions in Solutions -- 3.3. Reaction Mechanism -- 3.4. Quasi-equilibrium Approximation -- 3.5. Relationship Between Thermodynamics and Kinetics -- 3.6. Transition State Theory of Surface Reactions -- 3.7. Rates of Reactions on Nonideal Surfaces -- 3.8. Deterministic and Stochastic Models -- 3.9. Microkinetic Modeling -- 3.10. Compensation Effect -- 3.11. Isotope Effects -- 3.12. Examples and Exercises -- References -- 4.1. Steady State Kinetics of Complex Reactions -- 4.2. Basic Routes of Complex Reactions -- 4.3. Single-Route Steady-State Reaction -- 4.4. Topological Analysis of Complex Reactions -- 4.5. Electrical Analogy of Reaction Networks -- 4.6. Thermodynamic Consistency of Rate Constants for Complex Networks -- 4.7. Kinetic Aspects of Selectivity -- 4.8. Parallel Reactions: Kinetic Coupling -- 4.9. Reduction of Complexity -- 4.10. Polynomial Kinetics -- 4.11. Examples and Exercises -- References -- 5.1. Homogeneous Acid-Base Catalysis -- 5.2. Nucleophilic Catalysis -- 5.3. Catalysis by Metal Ions -- 5.4. Catalysis by Organometallic Complexes -- 5.5. Organocatalysis -- 5.6. Polymerization Catalysis -- 5.7. Examples and Exercises -- References -- 6.1. Enzymatic Catalysis -- 6.2. Cooperative Kinetics -- 6.3. Inhibition -- 6.4. Effects of pH -- 6.5. Single Molecule Enzymology -- 6.6. Enantioselectivity in Enzyme Catalyzed Reactions -- 6.7. Generalized Rate Laws for Enzymatic Reactions -- 6.8. Heterogeneous Systems/Immobilized Enzymes -- 6.9. Examples and Exercises -- References -- 7.1. Reactions on Ideal Surfaces -- 7.2. Reactions on Nonideal Surfaces -- 7.3. Selectivity -- 7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- 7.5. Solvent Effects -- 7.6. Ionic Species -- 7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- 7.8. Electrocatalytic Kinetics -- 7.9. Photocatalytic Kinetics -- 7.10. Nanokinetics -- 7.11. Examples and Exercises -- References -- 8.1. General -- 8.2. Combined Catalytic and Noncatalytic Reactions -- 8.3. Multiple Catalysts of the Same Type -- 8.4. Multiple Catalysts of Different Types -- 8.5. Examples and Exercises -- References -- 9.1. Transient Kinetics -- 9.2. Relaxation Methods -- 9.3. Temperature-Programmed Desorption -- 9.4. Oscillations -- 9.5. Dynamic Catalyst Changes -- 9.6. Examples and Exercises -- References -- 10.1. Catalytic Multi-Phase Systems -- 10.2. Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- 10.3. Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- 10.4. Catalytic Two-Phase Systems -- 10.5. Mass Transfer and Enzymatic Kinetics -- 10.6. External Mass Transfer -- 10.7. Internal Diffusion and Selectivity -- 10.8. Internal Diffusion and Deactivation -- 10.9. Elucidation of the Impact of Mass Transfer -- 10.10. Three-Phase Systems -- 10.11. Examples and Exercises -- References -- 11.1. Basic Principles -- 11.2. Heuristic Design of Experiments -- 11.3. Parameter Estimation: Classical Methods -- 11.4. Parameter Estimation: Regression -- 11.5. Numerical Strategies -- 11.6. Analysis of Parameters -- 11.7. Model Discrimination -- 11.8. Software -- 11.9. Case Studies -- References.
Bibliography noteIncludes bibliographical references and index.
Access restrictionAvailable only to authorized users.
Technical detailsMode of access: World Wide Web
Genre/formElectronic books.
LCCN 2017385977
ISBN9780444637536 hardcover
ISBN0444637532 hardcover